At St Ambrose Catholic Primary School Concord West, all staff work collaboratively within their roles to achieve the best possible outcomes for our community.
| Principal | Linda McFadden |
| Assistant Principal | Gennelle Mead |
| Religious Education Co-ordinator | Romina De Grazia |
| Co-ordinator | Carmel Romano |
| Co-ordinator | Sarina Testa |
| Senior School Support Officer | Anne-Louise Williams |
| School Support Officer | Carrie Farrugia |
| School Support Officer | Tanya Maronese |
| School Counsellor | Michelle Dunn |
| Information Systems Officer | Geoffrey Wang |
| Learning Support Officer | Pauline Angelis |
| Learning Support Officer | Kylie Antunes |
| Learning Support Officer | Rita Boumelhem |
| Learning Support Officer | Ellen Favorito |
| Learning Support Officer | Janeen Grysiewicz |
| Learning Support Officer | Lucy Phouisangiem |
| Learning Support Officer | Janene Stitt |
| Family Educator | Tania Chahoud |
| Music Teacher | Diana Kareh |
| Physical Education Teacher | Melissa Rathbone |
| Diverse Learning Needs Teacher | Laura Woodbury |
| Diverse Learning Needs Teacher | Teresa Vitagliani |
| EALD Teacher | Maria Mian |
| Reading Recovery Teacher | Josephine Celati |
| Teacher | Michele Couch |
| Teacher | Aneela Pereira |
| Teacher | Samantha Putnam |
| Teacher | Yolande DePalo |
| Teacher | Melissa Jennings |
| Teacher | Zoe Walton |
| Teacher | Amanda Tennina |
| Teacher | Roisin Drohan |
| Teacher | Clare Phillips |
| Teacher | Jack Simpson |
| Teacher | Hayden McIntyre |
| Teacher | Louise Panagis |
| Teacher | Paula Coleiro |